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Fundamentals of Chemical Reaction Engineering

File : pdf, 17 MB, 384 pages
by Mark E.Davis & Robert J. Davis

TOC

Chapt 1 The Basics of Reaction Kinetics for Chemical Reaction Engineering
1.1 The Scope of Chemical Reaction Engineering
1.2 The Extent of Reaction
1.3 The Rate of Reaction
1.4 General Properties of the Rate Function for a Single Reaction
1.5 Examples of Reaction Rates

Chapt 2 Rate Constants of Elementary Reactions
2.1 Elementary Reactions
2.2 Arrhenius Temperature Dependence of the Rate Constant
2.3 Transition-State Theory

Chapt 3 Reactors for Measuring Reaction Rates
3.1 Ideal Reactors
3.2 Batch and Semibatch Reactors
3.3 Stirred-Flow Reactors
3.4 Ideal Tubular Reactors
3.5 Measurement of Reaction Rates
3.5.1 Batch Reactors
3.5.2 Flow Reactors

Chapt 4 The Steady-State Approximation:Catalysis
4.1 Single Reactions
4.2 The Steady-State Approximation
4.3 Relaxation Methods

Chapt 5 Heterogeneous Catalysis
5.1 Introduction
5.2 Kinetics of Elementary Steps: Adsorption, Desorption, and Surface Reaction
5.3 Kinetics of Overall Reactions
5.4 Evaluation of Kinetic Parameters

Chapt 6
Effects of Transport Limitations on Rates of Solid-Catalyzed
Reactions
6.1 Introduction
6.2 External Transport Effects
6.3 Internal Transport Effects
6.4 Combined Internal and External Transport Effects
6.5 Analysis of Rate Data

Chapt 7 Microkinetic Analysis of Catalytic Reactions
7.1 Introduction
7.2 Asymmetric Hydrogenation of Prochiral Olefins
7.3 Ammonia Synthesis on Transition Metal Catalysts
7.4 Ethylene Hydrogenation on Transition Metals
7.5 Concluding Remarks

Chapt 8 Nonideal Flow in Reactors
8.1 Introduction
8.2 Residence Time Distribution (RTD)
8.3 Application of RTD Functions to the Prediction of Reactor Conversion
804 Dispersion Models for Nonideal Reactors
8.5 Prediction of Conversion with an AxiallyDispersed PFR
8.6 Radial Dispersion
8.7 Dispersion Models for Nonideal Flow in Reactors

Chapt 9 Nonisothermal Reactors
9.1 The Nature of the Problem
9.2 Energy Balances
9.3 Nonisothermal Batch Reactor
9.4 Nonisothermal Plug Flow Reactor
9.5 Temperature Effects in a CSTR
9.6 Stability and Sensitivity of Reactors Accomplishing Exothermic Reactions

Chapt 10
Reactors Accomplishing Heterogeneous Reactions
10.1 Homogeneous Versus Heterogeneous Reactions in Tubular Reactors
10.2 One-Dimensional Models for Fixed-Bed Reactors
10.3 Two-Dimensional Models for Fixed-Bed Reactors
lOA Reactor Configurations
10.5 Fluidized Beds with Recirculating Solids
App A
Review of Chemical Equilibria
A.1 Basic Criteria for Chemical Equilibrium of Reacting Systems
A.2 Determination of Equilibrium Compositions
App B
Regression Analysis
B.1 Method of Least Squares
B.2 Linear Correlation Coefficient
B.3 Correlation Probability with a Zero Y-Intercept
BA Nonlinear Regression
App C
Transport in Porous Media
C.1 Derivation of Flux Relationships in One-Dimension
C.2 Flux Relationships in Porous Media

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