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Chemical Dynamics

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TOC

1. Chemical Energetics
1-1 Introduction
1-2 Chemical Potential and Equilibrium

2. Application of the Chemical Potential to Acid
2-1 Ionization Equilibrium
2-2 Correlation with Gross Structure

3. Energetics of Acid Ionization in the Born-Haber Cycle
3-1 Introduction
3-2 The Born-Haber Cycle
3-3 Evaluation of the Born-Haber Terms

4. Energetics of Acid Ionization in a Cycle Including Electroreduction Potentials
4-1 Introduction
4-2 Measurement of Reduction Potentials
4-3 Analysis of Data

5 Rate Phenomena in Chemical Reactivity
5-1 Introduction
5-2 Reaction Mechanisms
5-3 Elementary Reactions

6 Elementary Reaction Processes in Gaseous and Liquid Systems
6-1 Recent Experimental and Theoretical Advances
6-2 Reactions in the Gaseous Phase
6-3 Reactions in Liquid Solutions

7 An Illustrative Chemical Reaction
7-1 The Iodide-Hypochlorite Reaction
7-2 Interpretation of the Rate Constant

8 Mechanisms and Rate Laws
8-1 The Rate-Determining Step
8-2 An Alternative Mechanism
8-3 A Further Look at the First Mechanism

9 The Interpretation of Rate Equations by Means of the Collision and the Transition State Theories 77
9-1 The Collision Theory
9-2 The Transition State Theory

10 Classification of Reactions, Reactants, and Mechanisms
10-1 Types of Reactions
10-2 Types of Reactants
10-3 Types of Mechanisms

11 Reaction Chemistry of Compounds of the Second-Row Elements with Emphasis on Boron
11-1 An Outline of Reactions of Compounds of Second-Row Elements
11-2 Mechanisms for Boron Chemistry

12 Heaction Chemistry of Compounds of Carbon, Nitrogen, Oxygen, and Fluorine
12-1 Mechanisms for Carbon
12-2 Mechanisms for Nitrogen
12-3 Mechanisms for Oxygen and Fluorine

13 Reactivi ty Correla tions
13-1 The Nature of Correlations
13-2 Specific Examples of Correlation: The Swain-Scott and Edwards Equations
13-3 Importance of the Nature of the Substrate
13-4 The Concept of Hard and Soft Acids and Bases

14 Substitution Reactions of Complexes of Metal Ions
14-1 Introduction
14-2 Overall Look at Metal Ion Rates
14-3 A Closer Look at the Energetics Involved in Dissociative and Associative Mechanisms
14-4 Eigand Substitution Dynamics in Square-Planar Complexes
14-5 Eigand Substitution Dynamics in Octahedral Complexes

15 Lectures on Frontier Areas in Chemical Dymamies
15-1 Chemical Dynamics in Really Simple Systems
15-2 Reactions of Atomic Carbon
15-3 Chemical Dynamics as Revealed by Nuclear Magnetic Resonance Spectroscopy
15-4 Electrochemical Dynamics

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